Product ID:MS-242AS ANTI-STATIC QUIK-FREEZE
MSDS Date:12/01/1989
FSC:6850
NIIN:00N022768
MSDS Number: BPZZV

MILLER-STEPHENSON CHEMICAL CO

GEORGE WASHINGTON HWY
DANBURY, CT 06810
US

Emergency Phone: 203-743-4447;800-424-9300(CHEMTREC)

Info Phone: 203-743-4447

Preparer: JANET STEPHENS

Cage: 18598

MILLER-STEPHENSON CHEMICAL CO INC

950 DANBURY, CT 06810 US

Telephone: 203-743-4447

Cage: 18598

BECAUSE OF POSS DISTURB OF CARD RHYTHM,

RTECS: 9999999ZZ

CAUTION ONLY IN SITUATIONS OF EMERGENCY LIFE SUPPORT.

RTECS: 9999999ZZ

VENT SHOULD BE USED IN LOW PLACES.

RTECS: 9999999ZZ

ALCOHOL (GRAIN ALCOHOL) IN 2000 ML WATER.

RTECS: 9999999ZZ

CHLORODIFLUOROMETHANE

CAS: 75-45-6

RTECS: PA6390000

Fraction By Weight: 99%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

(ORAL RAT) 5628 MG/KG

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 1%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

INGEST OF METHANOL MAY PRDCE DELAYED/IRREV IMPAIR

RTECS: 9999999ZZ

SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB

RTECS: 9999999ZZ

EPINEPHRINE MAY BE CONTRAINDICATED EXCPT LIFE-SUSTAIN

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 2
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF HIGH CONC OF VAP IS
HARMFUL & MAY CAUSE HEART IRREG, UNCON OR DEATH. INTENTIONAL MISUSE
CAN BE FATAL. VAP REDUCES O*2 AVAIL FOR BRTHG & IS HVR THAN AIR.
LIQ CONT CAN CAUSE FROSTBITE. UNT ESTED FOR SKIN/EYE IRRIT. ANIMAL
STUDIES SHOW INHALATION INCL EFTS ON THE CNS, LIVER, LUNGS,
KIDNEYS, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SPLEEN, CARDIAC SENSIT, DECRD BODY WT
GAIN & PARTIAL ANAESTHESIA. PRODUCES INCR OF TUMOR IN MALE RATS.
INHAL OF VAPS MAY CAUSE TEMP NERV SYS DEPRESS W/ANAESTHETIC EFTS
SUCH AS DIZZ, HDCH, CON FUSN, INCOORD & LOSS OF CONSCIOUSNESS.
HIGHER EXPOS TO THE VAPS MAY CAUSE TEMP ALTERATION OF THE HEARTS
(SUPP DATA)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING DISEASES
OF THE CENTRAL NERVOUS, CARDIOVASCULAR SYSTEM, RETINA OR LIVER MAY
HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE
EXPOSURES.

First Aid:INHAL:IF HIGH CONC ARE INHALED, IMMED REMOVE TO FRESH AIR.
KEEP PERS CALM. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT,
GIVE O*2. CALL A MD. EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST
15 MINS. CALL A MD. SKIN:FLUSH W/WATER. TREAT FOR FROSTBITE IF
NEC. INGEST:CALL A MD IMMED. INDUCE VOM TO LESSEN CHANCE OF VISION
IMPAIRMENT. AS AN ANTIDOTE, PROVIDE 100 ML OF 100 PROOF ETHYL (ING
6)

Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESSURE DEMAND SCBA &
FULL PROT EQUIP IF CYL RUPTURE/CONTENTS ARE RELSD UNDER FIRE
CNDTNS. USE WATER/FOG TO COOL CONTRS.
Unusual Fire/Explosion Hazard:OTHER BURNING MATL MAY CAUSE MS-242AS TO
BURN WEAKLY. EXTINGUISHANT FOR OTHER BURNING MATL IN AREA IS
SUFFICIENT TO STOP BURNING. THERMAL DECOMP (SUPP DATA)

Spill Release Procedures:VENTILATE AREA, ESPECIALLY LOW PLACES WHERE
HEAVY VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. USE NIOSH/MSHA
APPROVED SCBA FOR LARGE SPILL OR RELEASES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CLEAN, DRY AREA. DO NOT HEAT
ABOVE 125F. AVOID BREATHING VAPORS/LIQUID CONTACT W/SKIN & EYES.
Other Precautions:USE W/SUFFICIENT VENT TO KEEP EMPLOYEE EXPOS BELOW
RECOM LIMITS. NO SMKG IN AREA OF USE. DO NOT USE IN GEN VICINITY OF
ARC WELDING/OPEN FLAMES OR HOT SURF. HEAT &/OR UV RADIA MAY CAUSE
FORMATION OF CH LORIDES, FLUORIDES &/OR PHOSGENE .

Respiratory Protection:UNDER NORMAL USE CONDITIONS, NO RESPIRATORY
PROTECTION IS REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NORM VENT FOR STANDARD PROCEDURES IS GENERALLY ADEQ. LOC
EXHST SHOULD BE USED WHEN LGE AMTS ARE RELSD. MECH (ING 9)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:PROD MAY INCL FLUORIDES/CHLORIDES /PHOSGENE . HAZ DECOMP
PROD:HYDROFLUORIC ACIDS/POSS CARBONYL HALIDES. CHLORIDES
/FLUORIDES/PHOSGENE . EFTS OF OVEREXP:ELEC ACTIVITY W/IRREG PULS
E/PALPITATION/INADEQ CIRCULATION; OR FATALITY FROM GROSS OVEREXPOS.
SKIN CONT W/THE LIQ MAY CAUSE FROSTBITE. (ING 3)

HCC:G3
Boiling Pt:B.P. Text:-41F,-41C
Vapor Pres:151 @ 77F
Vapor Density:3.03 @ 77F
pH:NEUT
Evaporation Rate & Reference:>1 (CC14=1)
Solubility in Water:0.30% BY WT @ 77F
Appearance and Odor:CLEAR, COLORLESS LIQUIFIED GAS; SLIGHT ETHEREAL
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, POWDERED AL, BE, ZN, ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES & HIGH TEMPERATURES.
Hazardous Decomposition Products:PROD CAN BE DECOMPOSED BY HIGH TEMPS
(OPEN FLAMES, GLOWING METAL SURF, ETC) FORMING HYDROCHLORIC & (SUPP
DATA)

Waste Disposal Methods:COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.